Carbon dots as multifunctional fluorescent probe for Fe3+ sensing in ubiquitous water environments and living cells as well as lysine detection via "on-off-on" mechanism.

Iron and amino acids are essential nutrients for living organisms, and their deficiency or excess can cause a range of diseases. Therefore, there is considerable interest in developing sensing assays capable of detecting these nutrients with sensitivity, selectivity, and multifunctionality even in complex environments. In this report, hydrothermally synthesized blue fluorescent carbon dots (C-dots) from zinc gluconate were utilized for the detection of Fe3+ and lysine via "on-off" and "on-off-on" mechanisms, respectively. Specifically, the Fe3+ sensing assay achieved a broad linear range of 0-200 µM and a low limit of detection (LOD) of 1.9 µM. It is worth mentioning that the assay was also well adapted to natural aqueous environments (e.g., lake water), and its linear detection range could be extended to 0-1000 µM with a LOD of 3.3 µM. Furthermore, the assay was also effective for intracellular Fe3+ tracking. Most importantly, the assay could also be applied for the quantitative detection of lysine with a linear range of 0-1200 µM and LOD of 8.6 µM. Systematic mechanistic studies revealed that Fe3+ sensing was based on a static quenching process between C-dots and Fe3+, whereas a stronger complexation might have formed between Fe3+ and Lys, leading to the release of C-dots and thus the recovery of fluorescence.

Solid-State, Hectogram-Scale Preparation of Red Carbon Dots as Phosphor for Energy-Transfer-Induced High-Quality White LEDs with CRI of 97.

In this study, pre-crystallization-controlled, solid-state preparation of red carbon dots (C-dots) from o-phenylenediamine on a hectogram scale with a 94% yield is reported. Highly efficient red phosphor (C-dots@MCC) is obtained by dispersing the C-dots in microcrystalline cellulose, which matched extremely well with the commercial Y3 Al5 O12 :Ce3+ (YAG) phosphor. White light-emitting diodes (WLEDs) fabricated from the two phosphors emitted warm white light with a correlated color temperature of 3845 K, CIE color coordinates of (0.38, 0.37), and an extremely high color rendering index (CRI) of 95, outperforming all the reported YAG-derived WLEDs. Furthermore, the CRI value of the WLED can be further increased to 97 after fine-tuning, which is the highest CRI for WLEDs of any C-dots derived devices reported so far. The superior performance of the WLED is attributed to a delicate energy transfer between YAG and C-dots@MCC. Most importantly, the WLED maintained excellent stabilities under varied currents, working durations, moistures, and temperatures.

Synthesis Mechanisms, Structural Models, and Photothermal Therapy Applications of Top-Down Carbon Dots from Carbon Powder, Graphite, Graphene, and Carbon Nanotubes.

In this study, top-down syntheses of carbon dots (CDs) from four different carbon precursors, namely, carbon nano powders, graphite, graphene, and carbon nanotubes, were carried out. Systematic study demonstrated that the optical properties and surface functionalities of the CDs were quite similar and mainly influenced by the synthesis method, while the sizes, morphologies, chemical compositions, and core structures of the CDs were heavily influenced by the carbon precursors. On the basis of these studies, the formation processes and structural models of these four top-down CDs were proposed. The cell cytotoxicity and photothermal conversion efficiency of these CDs were also carefully evaluated, demonstrating their potential applications in photothermal therapy.

Facile and Sensitive Detection of Nitrogen-Containing Organic Bases with Near Infrared C-Dots Derived Assays.

In this article, we have designed both colorimetric (including solution and test paper type) and spectral sensors (including UV-vis and PL type) for the quick and sensitive detection of general nitrogen-containing organic bases (NCOBs); the limit of detection could reach as low as 0.50 nM. NCOBs included 11 examples, covering aliphatic and aromatic amines, five- and six-membered heterocyclics, fused-ring heterocyclics, amino acids, and antibiotics. Furthermore, the assays demonstrated high reliability in sensing NCOBs and excellent ability to distinguish NCOBs from oxygen and sulfur containing organics. The assays developed could find important applications for the detection of NCOBs in the fields of biomedicine, chemistry, and agriculture.

Switchable encapsulation of polysulfides in the transition between sulfur and lithium sulfide.

Encapsulation strategies are widely used for alleviating dissolution and diffusion of polysulfides, but they experience nonrecoverable structural failure arising from the repetitive severe volume change during lithium-sulfur battery cycling. Here we report a methodology to construct an electrochemically recoverable protective layer of polysulfides using an electrolyte additive. The additive nitrogen-doped carbon dots maintain their "dissolved" status in the electrolyte at the full charge state, and some of them function as active sites for lithium sulfide growth at the full discharge state. When polysulfides are present amid the transition between sulfur and lithium sulfide, nitrogen-doped carbon dots become highly reactive with polysulfides to form a solid and recoverable polysulfide-encapsulating layer. This design skilfully avoids structural failure and efficiently suppresses polysulfide shuttling. The sulfur cathode delivers a high reversible capacity of 891 mAh g-1 at 0.5 C with 99.5% coulombic efficiency and cycling stability up to 1000 cycles at 2 C.